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The electroplating process consists of two main steps: (i) the mass transport of chromium ions through the electrolyte to the surface of the electrode, and (ii) the reduction of chromium ions at the cathode through chemical reactions. . The fundamental equations needed to model the system are: 2.1 Conservation Balances. The conservation of mass.
Analytical Methods: Hexavalent Chromium Plating Solutions. Mary C. Traficante, Atotech USA Inc., Rock Hill, SC. This is a brief review of accepted analytical methods for chromium plating solutions. The relative standard deviation (RSD) of certain methodologies is presented.
This chapter contains sections titled: Principles. Theory of Chromium Electrodeposition. Hexavalent Chromium. Methods of Operations of Chromium Plating Solutions. Mixed Catalysts and Selfregulating Baths. Chromic Acid Baths: Operating Conditions. Throwing Power.
Hexavalent chromium plating baths are the most widely used baths to deposit chromium on metal. Hexavalent chromium baths are composed of chromic acid, sulfuric acid, and water.
Chromium plating is traditionally made from a solution of chromic acid (CrO3 which forms H 2 CrO 4 after dissolving in water) and sulfuric acid (H 2 SO 4) using insoluble anodes. The chromium is reduced to metal from the hexavalent state due to the catalytic effect of sulfate ions.
Air emissions during the electroplating process contain hexavalent chromium (Cr+6) - a known carcinogen, furthermore the process is energy-intensive... Contexts in source publication....
2 Ιαν 2011 · Processes using the chemical reduction of hexavalent chromium to obtain electrolytic solutions of high Cr+3 concentrations. Cr(VI) reduction could be done using SO 2 or alcohol, to obtain trivalent chromium ions.
