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Eh-pH-diagrams show the thermodynamic stability areas of different species in an aqueous solution. Stability areas are presented as a function of pH and electrochemical potential scales. Usually the upper and lower stability limits of water are also shown in the diagrams with dotted lines.
30 Νοε 2021 · Abstract. Speciation diagrams are useful in determining the effects of conditions on the distribution of species. For example in the sulfate/water system it is useful to know the available sulfate ion concentration as a function of pH. Download chapter PDF.
29 Αυγ 2023 · Most sulfates, including those of \(\ce{Na^{+}}\), \(\ce{K^{+}}\), and \(\ce{NH4^{+}}\), are soluble in water. Exceptions that are insoluble are white lead(II) sulfate and white barium sulfate: \[\ce{BaSO4(s) <=> Ba2+(aq) + SO42-(aq)} \nonumber \] with \(K_{sp} = 1.4 \times 10^{-8}\) \[\ce{PbSO4(s) <=> Pb2+(aq) + SO42-(aq)} \nonumber \]
There are several tests for sulfate ion to identify from other anions in qualitative analysis. Some of metal sulfate compounds are soluble in water and some metal sulfates form precipitates. Sulfate compounds of several d block metal cations form colours.
Learning Objectives. By the end of this section, you will be able to: Predict whether a salt solution will be acidic, basic, or neutral. Calculate the concentrations of the various species in a salt solution. Describe the acid ionization of hydrated metal ions. Salts with Acidic Ions.
16 Ιουλ 2023 · Common examples are HCl, HBr, HI and H 2 SO 4, all of which react with H 2 O to form large concentrations of ions. A solution of HCl, for example, conducts even better than one of NaCl having the same concentration.
In weathering or contact with aerated water, the sulfides are oxidized to yield sulfate ions which are carried off in the water. Sulfate is carried to bodies of water by rain and through solution of sulfate compounds in sedimentary geologic formations within the drainage basin.
