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1. Calculate the change in entropy of a large vat of molten copper when 50 J of energy is removed reversible from it as heat at 1100 °C. 2. Calculate the change in entropy of 1.0 L of water at 0 °C when it absorbs 235 J of energy from a heater.
Worksheet on Entropy and Free Energy. Define entropy in your own words, and list the variables or conditions that you must consider when comparing the entropy of two substances, or when trying to determine the relative change in entropy.
Calculate the standard enthalpy change, entropy change, and free-energy change at 2980C for each of the following reactions by using data in the Appendix in the back of your book.
Determine the standard entropy change for the decomposition of one mole of solid calcium carbonate, forming solid calcium oxide and carbon dioxide gas. SOLUTION
Worksheet Chem 160 Chapter 17: Thermodynamics: Entropy, Free Energy, and Equilibrium 1. What is a spontaneous process? What determines spontaneity? Define Gibb’s free energy, enthalpy, and entropy, and the relationship between them. 2. Predict the sign of ΔS in the following processes. Briefly explain your answer: a. 3 O 2 (g) ⇌ 2 O 3 (g ...
3 Νοε 2018 · The unit of entropy is J K-1 mol-1. ∆Ssystem ̊ = Σ S ̊products - ΣS ̊reactants. Example. Calculate ∆S ̊ for the following reaction at 25 ̊C: 2Fe2O3 (s) + 3C (s) 4Fe (s) + 3CO2 (g) ∆S ̊ = S ̊products - S ̊reactants. = (3 x 213.6 + 4 x 27.3) – (2 x 87.4 + 3 x 5.7) = + 558.1 J K-1 mol-1 = + 558 J K-1 mol-1 (3 S.F.) [Fe2O3] = 87.4 J K-1 mol-1.
Entropy is a thermodynamic function that describes the number of arrangements (positions and/or energy levels) that are available to a system existing in a given state. Entropy is closely related to probability.