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6 Φεβ 2015 · Understanding metalloenzymes: A synthetic Fe III-OCl complex has been generated and spectroscopically characterized at room temperature. Such nonheme iron(III) hypohalite intermediates have been implicated in biological halogenation reactions and may offer clues to understanding the activity of iron halogenases.
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Iron(III) Hypochlorite Intermediates** Apparao Draksharapu,...
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An iron boost: High-spin iron(III) iodosylarene complexes...
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Hydrates of iron(III) chloride do not readily yield anhydrous ferric chloride. Attempted thermal dehydration yields hydrochloric acid and iron oxychloride. In the laboratory, hydrated iron(III) chloride can be converted to the anhydrous form by treatment with thionyl chloride [17] or trimethylsilyl chloride: [18]
First, iron scrap is dissolved in the melt at 600 °C and oxidized to iron(II) chloride by iron(III) chloride. Iron(II) chloride then reacts with chlorine to yield iron(III) chloride, which sublimes and is collected in cooled condensation chambers.
Iron (III) Hypochlorite. Note: Fill in one box to get results in the other box by clicking "Calculate" button. Data may be separated by semicolon (;), space, tab, or in separated lines.
3 Μαρ 2015 · We show that iron(III) hypohalite complexes are formed readily in water at low pH values from [Fe II (OH 2)(MeN4Py)] 2+ (Scheme 1)11, 12 upon reaction with NaOCl or NaOBr at room temperature.13 The Fe III –OX species was found to undergo subsequent slower conversion into a relatively stable Fe IV =O analogue within several minutes.
27 Μαρ 2015 · The species observed and the pathways involved offer insight into and, importantly, a spectroscopic database for the investigation of iron halogenases. Keywords: EPR spectroscopy; Raman spectroscopy; hypochlorite; iron; metalloenzymes.
6 Φεβ 2015 · The nonheme high-spin iron(III) iodosylarene intermediates are highly reactive oxidants capable of activating strong CH bonds of alkanes; the reactivity of the iron(III) iodosylarene...
