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PubChem is the world's largest collection of freely accessible chemical information. Search chemicals by name, molecular formula, structure, and other identifiers. Find chemical and physical properties, biological activities, safety and toxicity information, patents, literature citations and more.
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7 Αυγ 2020 · Briefly, fractionated oligosaccharides underwent acid hydrolysis with 4 M TFA for 2 h at 100 °C. The samples were dried to completion by vacuum centrifugation.
Reaction of a phosphinobenzylsilane compound with ruthenium complexes leads to C–H and/or Si–H activation. The new complex Ru{η 2-H–SiMe 2 CH(o-C 6 H 4)PPh 2} 2 (5) was isolated and X-ray, NMR and DFT studies reveal that 5 displays two agostic Si–H interactions and two carbon-metallated bonds.
30 Μαΐ 2012 · The attainment of two new nanoclusters, Au 39 (SC 2 H 4 Ph) 29 and Au 40 (SC 2 H 4 Ph) 30, demonstrates the feasibility of controlling cluster size via controlled reduction. Herein, we discuss some insights obtained regarding the synthetic processes of Au 20, Au 24, and Au 39/40.