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When analyzing an IR spectrum, it is helpful to overlay the diagram below onto the spectrum with our mind to help recognize functional groups. Figure 1. Group frequency and fingerprint regions of the mid-infrared spectrum. The region of the infrared spectrum from 1200 to 700 cm-1 is called the fingerprint region.
Table of Characteristic IR Absorptions m=medium, w=weak, s=strong, n=narrow, b=broad, sh=sharp ... –1 bond functional group 3640–3610 (s, sh) O–H stretch, free hydroxyl alcohols, phenols 3500–3200 (s,b) O–H stretch, H–bonded alcohols, phenols 3400–3250 (m) N–H stretch 1˚, 2˚ amines, amides 3300–2500 (m) O–H stretch ...
Typical IR Absorption Frequencies For Common Functional Groups. Bond. Functional Group. Frequency in cm −1 (Intensity*) C–H. Alkane. 3000–2850 (s) –CH 3. 1450 and 1375 (m)
By learning where characteristic functional-group absorptions occur, it’s possible to get structural information from IR spectra. Table 12.1 lists the characteristic IR bands of some common functional groups.
The IR spectrum of caffeine offers a wealth of information about its molecular structure and characteristics. By understanding the peaks and absorption bands, researchers can gain insights into the purity, stability, and therapeutic potential of caffeine-containing products.
21 Οκτ 2024 · After completing this section, you should be able to use an infrared spectrum to determine the presence of functional groups, such as alcohols, amines and carbonyl groups, in an unknown compound, given a list of infrared absorption frequencies.
Infrared spectroscopy is the study of the interaction of infrared light with matter. The fundamental measurement obtained in infrared spectroscopy is an infrared spectrum, which is a plot of measured infrared intensity versus wavelength (or frequency) of light.
