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write an equation to describe the reaction of an acid anhydride with each of the following: water, alcohol, ammonia, a primary or secondary amine, lithium aluminum hydride. identify the product formed when a given acid anhydride is reacted with any of the reagents listed in Objective 4, above.
This page looks at the reactions of acid anhydrides with water, alcohols and phenols (including the manufacture of aspirin). These reactions are all considered together because their chemistry is so similar.
23 Ιαν 2023 · This page looks at the reactions of acid anhydrides with water, alcohols and phenols (including the manufacture of aspirin). These reactions are all considered together because their chemistry is so similar.
An Acid anhydride can be defined as a non-metal oxide which forms an acidic solution when reacted with water. In organic chemistry, it is a functional group consisting of 2 acyl groups combined by an oxygen atom.
Acid Anhydrides react with water to form carboxylic acids. General Reaction. Example 1: Mechanism. 1) Nucleophilic Attack by the water molcule. 2) Deprotonation by pyridine. 3) Leaving group removal. 4) Protonation of the carboxylate. Acid Anhydrides react with alcohols to form esters. Reactions of anhydrides use Pyridine as a solvent. Example 1:
Thus, acid anhydrides react with water to form acids, with alcohols to form esters, with amines to form amides, and with LiAlH 4 to form primary alcohols. Only the ester- and amide-forming reactions are commonly used, however.
Acid anhydrides are made from two carboxylic acid groups joined together. To form an acid anhydride, a water molecule is lost in a condensation reaction between two carboxylic acids. This is why acid anhydrides are called anhydride – lack of water. Reactions of Acid Anhydrides.
