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Solvation is the interaction of a solvent with the dissolved solute—in the case of water, solvation is often referred to as hydration. Solvent polarity is the most important factor in determining how well it solvates a particular solute.
The solvation effect makes the reaction endothermic, indicating that the reaction preferably proceeds at the solid/liquid interface, that is, the surface of the deposits, rather than in the solution bulk.
16 Ιουλ 2020 · The most evident solvation effect is the enhancement of the reactant concentrations at the interface, because neutral molecules and soft anions tend to stabilize there, favoured...
18 Φεβ 2024 · Since about 1980, one has safely been able to say that almost everyone who studies solvation uses the new definition of the solvation process and the corresponding Gibbs energy of solvation, denoted ∆ μ α ∗.
17 Δεκ 2015 · Solvation does not only change the properties of reactants and products, but also affects transition states by influencing the thermodynamics, the kinetics, and the product selectivity in liquid-phase reactions.
3 Σεπ 2024 · The solvation of any solute (electrolyte or otherwise) entails a disruption of the system microstructure resulting from the solute–solvent intermolecular interaction asymmetry, described formally and unambiguously as a finite local density perturbation (i.e., a short-range or direct effect) whose propagation across the system (i.e., a longer ...
10 Δεκ 2020 · A significant metal dependence on aqueous solvation effects was observed that suggests solvation effects must be studied in detail for every reaction system.