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Air emissions during the electroplating process contain hexavalent chromium (Cr+6) - a known carcinogen, furthermore the process is energy-intensive... Contexts in source publication....
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The electroplating process consists of two main steps: (i) the mass transport of chromium ions through the electrolyte to the surface of the electrode, and (ii) the reduction of chromium ions at the cathode through chemical reactions. . The fundamental equations needed to model the system are: 2.1 Conservation Balances. The conservation of mass.
2 Ιαν 2011 · Processes using the chemical reduction of hexavalent chromium to obtain electrolytic solutions of high Cr+3 concentrations. Cr(VI) reduction could be done using SO 2 or alcohol, to obtain trivalent chromium ions.
Summary. This chapter contains sections titled: Principles. Theory of Chromium Electrodeposition. Hexavalent Chromium. Methods of Operations of Chromium Plating Solutions. Mixed Catalysts and Selfregulating Baths. Chromic Acid Baths: Operating Conditions. Throwing Power.
Chromium plating is traditionally made from a solution of chromic acid (CrO3 which forms H 2 CrO 4 after dissolving in water) and sulfuric acid (H 2 SO 4) using insoluble anodes. The chromium is reduced to metal from the hexavalent state due to the catalytic effect of sulfate ions.
Hexavalent chromium is a known inhalation irritant and associated with respiratory cancer and it is primarily associated with the chrome plating and anodizing process and emissions from chromate-treated cooling towers.
Hexavalent chromium plating baths are the most widely used baths to deposit chromium on metal. Hexavalent chromium baths are composed of chromic acid, sulfuric acid, and water.
