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  1. The first law of thermodynamics is given as \(\Delta U = Q - W\), where \(\Delta U\) is the change in internal energy of a system, \(Q\) is the net heat transfer (the sum of all heat transfer into and out of the system), and \(W\) is the net work done (the sum of all work done on or by the system).

  2. The law distinguishes two principal forms of energy transfer, heat and thermodynamic work, that modify a thermodynamic system containing a constant amount of matter. The law also defines the internal energy of a system, an extensive property for taking account of the balance of heat and work in the system.

  3. An energy balance calculation is necessary to determine the heating and cooling duties in the flowsheet. An estimate of the heat content of each stream can be rapidly determined by making the following assumptions: 1. The vapor and liquid streams have ideal properties.

  4. Calorimetry is the science associated with determining the changes in energy of a system by measuring the heat exchanged with the surroundings. Now that sounds very textbooky; but in this last part of Lesson 2, we are going to try to make some meaning of this definition of calorimetry.

  5. Track and visualize how energy flows and changes through your system. Explore how heating and cooling iron, brick, water, and olive oil adds or removes energy. See how energy is transferred between objects.

  6. Learning Objectives. By the end of this section, you will be able to: Explain some phenomena that involve conductive, convective, and radiative heat transfer. Solve problems on the relationships between heat transfer, time, and rate of heat transfer. Solve problems using the formulas for conduction and radiation.

  7. Explore thermodynamics, how energy is changed from other forms (like radiant energy from the sun) to heat. Measure how the sun's energy strikes an everyday object and becomes transformed as infrared photons, which you can measure as heat. Or experiment with how to keep things cool.